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Friday, December 1, 2017

Industrial Chemistry(Ph.D)


1.          With increase in impurities in metals, their corrosion resistances
A)                Increase
B)                Decrease
C)                Remain same
D)                May increase or decrease; depending on the type of metal

2.          The most important requirement for aluminium industry is the availability of cheap
A)                Ore                                          B) Electrical power      
C) Labour                                            D) Abundant water

3.          Neutrons are present in all atoms except that of
A)                He       B) C                             C) H                            D) Ar

4.          The Fourier number (defined as a.t/L2) is used in the analysis of problem involving heat transfer by
A)                Forced convection                  B) Natural convection
C) Transient conduction                      D) Steady state conduction

5.          For gases, the thermal conductivity increases with temperature rise. For liquids, with increase in concentration, its thermal conductivity generally
A)                Decreases                                B) Increases
C) Remains unchanged                       D) Increases exponentially

6.          Among liquids, water has a comparatively high value of thermal conductivity, due to its
A)                Low density                            B) High viscosity
C) Partial ionisation                             D) Dense structure

7.          Pick out the wrong statement.
A)                The mole fraction of solute is directly proportional to the molality of a 'dilute'             solution
B)                For a non-reacting binary mixture of ideal gases, the partial pressure        distribution of both components is nonlinear in the case of steady state        unimolal unidirectional diffusion.
C)                Azeotropes obey Raoult's law at all temperature.
D)                The relative volatility of a binary mixture at the azeotropic composition is 1.

8.          Leaching of sugar from sugar beets is done by
A)                Hot water                                B) Hexane
C) Dilute H2SO4                                            D) Lime water

9.          What is the reflux ratio at total reflux?
A)                Zero                 B) Infinity       C) Unity                      D) Data insufficient

10.      Commercial fertilisers are available mostly in the form of
A)                Powder                        B) Granules     C) Lumps                    D) Flakes

11.      Reaction of dilute sulphuric acid with phosphate rock produces
A)                Phosphoric acid                                   B) Superphosphate
C) Triple superphosphate                     D) Gypsum

12.      Liquid ammonia is not used as such a fertiliser in tropical countries like India, because
A)                Its N2 content is very low       B) It is very costly
C) It will evaporate on spraying          D) It is not available

13.      Internal energy change of a system over one complete cycle in a cyclic process is
A)                Zero                 B) +ve             C) –ve                         D) dependent on the path

14.      Out of the following refrigration cycles, which one has the minimum COP (Co-efficient of performance)?
A)                Air cycle           
B)                Carnot cycle
C)                Ordinary vapour compression cycle
D)                Vapour compression with a reversible expansion engine

15.      "At the absolute zero temperature, the entropy of every perfectly crystalline substance becomes zero". This follows from the
A)                Third law of thermodynamics             B) Second law of thermodynamics
C) Nernst heat theorem                       D) Maxwell's relations

16.      Which of the following is a thermodynamic property of a system?
A)                Concentration B) Mass           C) Temperature            D) Entropy

17.      While dissolving a gas into a liquid at a constant temperature, the ratio of the concentration of the gas in the solution phase and in the gaseous phase is
A)                Infinity                        B) Unity          C) Constant                 D) Negative

18.      Which of the following exemplifies an adiabatic process?
A)                Melting of ice                         B) Condensation of alcohol vapor
C) Sudden bursting of a cycle tube      D) Evaporation of water

19.      During combustion of gaseous fuels, deficiency of air
A)                Lengthens the flame                
B)                Tends to shorten the flame
C)                Does not affect the flame length
D)                Increases the flame temperature

20.      Low temperature carbonisation
A)                Is mainly for producing the smokeless domestic coke
B)                Is meant for the production of 'metallurgical coke'
C)                Produces higher quantity of gas than high temperature carbonisation D) Produces less quantity of tar than high temperature carbonisation

21.      Main constituents of purified Lurgi gas are
A)                H2, CmHn & CO2                                            B) CO, H2 & CH4
C) CO2, O2 & CO                                D) N2, H2 & CO2

22.      The cuprous chloride used in orsat apparatus can absorb
A)                Only CO                                 B) Both CO and CO2
C) Both CO and O2                                      D) all CO, CO2, and O2.

23.      Which of the following is a lean fuel gas?
A)                Coke oven gas                                     B) LPG
C) Blast furnace gas                            D) Natural gas

24.      Fireclay bricks are not used in the
A)                Beehive coke oven                   
B)                By-product coke oven walls C) Combustion chamber of B.F. stoves D) Coke oven regenerators.

25.      Caprolactum, a raw material for the manufacture of nylon-6, is produced from
A)                Phenol             B) Naphthalene           C)  Benzene                D) Pyridine

26.      The monomer of poly vinyl chloride (PVC) is
A)                Chloroethene                           B) Ethylene dichloride
C) Ethyl chloride                                 D) Chloroform

27.      Buna-S is also known as
A)                Teflon B) PTFE                      C) SBR                       D) Polycrylates

28.      Automobile steering wheels are normally made of
A)                Cellulose acetate                                 B) Cellulose nitrate
C) PVC                                                D) High density polythene

29.      In a cross linked polymer, the monomeric units are linked together to constitute a three dimensional network. Which of the following is a cross-linked polymer?
A)                Bakelite (phenol formaldehyde)         B) Polyester
C) Polythene                            D) Nylon-6

30.      Polymethyl methacrylate (PMMA) is known as
A)                Bakelite           B) Teflon                     C) Perspex                   D) Nylon-6

31.      Neoprene is the trade name of
A)                Polyurethane                           B) Phenol formaldehyde
C)  Polychlorophrene              D) Styrene butadiene rubber (SBR)

32.      Epoxy resin is
A)                Not used for surface coating B) A good abrasive
C) An elastomer                                  D) A polyester

33.      The major component of acrylic fibres is
A)                Polyamides                              B) Polyolefins              
C) Polyacrylonitrile                             D) Polyesters

34.      Which is the most undesirable component in kerosene?
A)                Aromatics                                B) i-paraffins
C) n-paraffins                                      D) Naphthenes
35.      Which of the following fractions of a crude oil will have the maximum gravity API   (i.e. °API)?
A)                Diesel                                     B) Gasoline
C) Atmospheric gas oil                        D) Vacuum gas oil

36.      Pour point and freezing point is equal for
A)                Petrol   B) Diesel                     C) Water                     D) Crude petroleum

37.      Visbreaking process is used mainly for making
A)                High cetane diesel                   B) High octane gasoline
C) Fuel oil                                            D) Smoke free kerosene

38.      Stabilisation of gasoline (petrol) means
A)                Removal of dissolved gases from it
B)                Increasing its oxidation stability
C)                Improving its lead susceptibility
D)                Increasing its vapour pressure

39.      In petroleum refining, the process used for conversion of hydrocarbons to aromatics is A) Catalytic cracking                     B) Catalytic reforming
C) Hydrotreating                                 D) Alkylation

40.      Octane number of gasoline is a measure of its
A) Resistance to knock             
B) Ignition delay
C) Ignition temperature            

41. Catalyst used in catalytic reforming is
D) Smoke point
A) Platinum on alumina            
B) Nickel
C) Iron                                      
D) Aluminium chloride

42.  The first crude oil refinery of India is located at
A)   Naharkatiya                                    B) Digboi
C) Kochin                                            D) Madras

43.  Oxidation of SO2 to SO3 is favoured by
A)   Low temperature and low pressure
B)   Low temperature and high pressure
C)   High temperature and low pressure
D)  High temperature and high pressure

44.  Starting raw material for the manufacture of alum is
A)   Alumina                                          B) Gypsum
C) Bauxite                                           D) Ammonium bicarbonate

45.  Salt cake is chemically represented by
A) Na2SO4         B) CaSO4. ½ H2O       C) MgSO4

46. Which of the following sugars is the sweetest?

D) BaSO4
A) Glucose       B) Fructose                  C) Sucrose

47. All enzymes are made of

D) Lactose
A)  Fats            B) Carbohydrates        C) Proteins

D) Amino acids

48.  Styrene is produced from ethyl benzene by the process of
A)   Dehydrogenation              B) Oxidation
C) Alkylation                          D) Dehydration

49.  Gelatine which is a nitrogenous organic protein is obtained by the hydrolysis of
A)   Collagen     B) Tannin                    C) Molasses                 D) Carbohydrate

50.  Haemoglobin is a/an
A)   Amino acid                                     B) Biological catalyst
C) Protein                                            D) Enezyme


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